sample webservices hosted on web

http://www.webservicex.net/WS/wscatlist.aspx

http://www.webservicex.net/globalweather.asmx?WSDL

http://www.webservicex.net/CurrencyConvertor.asmx?WSDL

http://webservices.daehosting.com/services/TemperatureConversions.wso?WSDL

SOAPUI testing

http://www.soapui.org/ - download SOAPUI 4.5.1 from this link(Windows 32-bit installer)

http://www.soapui.org/Downloads/latest-release.html  - download SOAPUI Pro4.5.1(Window 32- bit installer)
http://www.filehippo.com/download_jre_32/ - JDK Software
http://www.filehippo.com/download_notepad/ - notepad++ software